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Approaching the commercial threshold of solar water splitting toward hydrogen by III-nitrides nanowires

《能源前沿（英文）》 doi: 10.1007/s11708-023-0870-z

摘要： Approaching the commercial threshold of solar water splitting toward hydrogen by III-nitrides nanowires

关键词： threshold solar water     splitting hydrogen III    

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Ga(X)N/Si nanoarchitecture: An emerging semiconductor platform for sunlight-powered water splitting towardhydrogen

《能源前沿（英文）》 doi: 10.1007/s11708-023-0881-9

摘要： Sunlight-powered water splitting presents a promising strategy for converting intermittent and virtually unlimited solar energy into energy-dense and storable green hydrogen. Since the pioneering discovery by Honda and Fujishima, considerable efforts have been made in this research area. Among various materials developed, Ga(X)N/Si (X = In, Ge, Mg, etc.) nanoarchitecture has emerged as a disruptive semiconductor platform to split water toward hydrogen by sunlight. This paper introduces the characteristics, properties, and growth/synthesis/fabrication methods of Ga(X)N/Si nanoarchitecture, primarily focusing on explaining the suitability as an ideal platform for sunlight-powered water splitting toward green hydrogen fuel. In addition, it exclusively summarizes the recent progress and development of Ga(X)N/Si nanoarchitecture for photocatalytic and photoelectrochemical water splitting. Moreover, it describes the challenges and prospects of artificial photosynthesis integrated device and system using Ga(X)N/Si nanoarchitectures for solar water splitting toward hydrogen.

关键词： Ga(X)N/Si nanoarchitecture     artificial photosynthesis     water splitting     solar toward hydrogen    

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Photocatalysis: from solar light to hydrogen energy

《能源前沿（英文）》 2021年 第15卷 第3期   页码 565-567 doi: 10.1007/s11708-021-0784-6

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Unravelling the bottleneck of phosphonic acid anchoring groups aiming toward enhancing the stabilityand efficiency of mesoscopic solar cells

《化学科学与工程前沿（英文）》 2022年 第16卷 第7期   页码 1060-1078 doi: 10.1007/s11705-021-2117-z

摘要： Novel near-infrared sensitizers with different anchoring groups aiming toward improved stability and efficiency of dye-sensitized solar cells were synthesized. Adsorption of these dyes on the mesoporous TiO2 surface revealed the dye adsorption rate of –CH=CH–COOH (SQ-139)>–CH=C(CN)COOH (SQ-140)>–PO3H2 (SQ-143)>–CH=C(CN)PO3H2 (SQ-148)>–CH=C(CN)PO3H–C2H5 (SQ-157)>–PO3H–C2H5 (SQ-151)>–CH=CH–COOH(–PO3H2) (SQ-162). The binding strength of these dyes on mesoporous TiO2 as investigated by dye desorption studies follows SQ-162>SQ-143>SQ-148>SQ-139>SQ-157~SQ-151>SQ-140 order. The acrylic acid anchoring group was demonstrated to be an optimum functional group owing to its fast dye adsorption rate and better binding strength on TiO2 along with good photoconversion efficiency. Results of dye binding on TiO2 surface demonstrated that SQ-162 bearing double anchoring groups of phosphonic and acrylic acid exhibited>550 times stronger binding as compared to dye SQ-140 having cyanoacrylic acid anchoring group. SQ-140 exhibited the best photovoltaic performance with photon harvesting mainly in the far-red to near-infrared wavelength region having short circuit current density, open-circuit voltage and fill factor of 14.28 mA·cm–2, 0.64 V and 0.65, respectively, giving the power conversion efficiency of 5.95%. Thus, dye SQ-162 not only solved the problem of very poor efficiency of dye bearing only phosphonic acid while maintaining the extremely high binding strength opening the path for the design and development of novel near-infrared dyes with improved efficiency and stability by further increasing the π-conjugation.

关键词： anchoring groups     adsorption behaviour     dye-binding strength     squaraine dyes     dye-sensitized solar cells    

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Revisiting solar hydrogen production through photovoltaic-electrocatalytic and photoelectrochemical water

《能源前沿（英文）》 2021年 第15卷 第3期   页码 596-599 doi: 10.1007/s11708-021-0745-0

摘要： Photoelectrochemical (PEC) water splitting is regarded as a promising way for solar hydrogen production, while the fast development of photovoltaic-electrolysis (PV-EC) has pushed PEC research into an embarrassed situation. In this paper, a comparison of PEC and PV-EC in terms of efficiency, cost, and stability is conducted and briefly discussed. It is suggested that the PEC should target on high solar-to-hydrogen efficiency based on cheap semiconductors in order to maintain its role in the technological race of sustainable hydrogen production.

关键词： hydrogen production     photovoltaic     electrocatalysis     photoelectrocatalysis     water splitting    

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Thermodynamic assessment of hydrogen production via solar thermochemical cycle based on MoO

Jiahui JIN, Lei WANG, Mingkai FU, Xin LI, Yuanwei LU

《能源前沿（英文）》 2020年 第14卷 第1期   页码 71-80 doi: 10.1007/s11708-019-0652-9

摘要： Inspired by the promising hydrogen production in the solar thermochemical (STC) cycle based on non-stoichiometric oxides and the operation temperature decreasing effect of methane reduction, a high-fuel-selectivity and CH -introduced solar thermochemical cycle based on MoO /Mo is studied. By performing HSC simulations, the energy upgradation and energy conversion potential under isothermal and non-isothermal operating conditions are compared. In the reduction step, MoO : CH = 2 and 1020 K< <1600 K are found to be most favorable for syngas selectivity and methane conversion. Compared to the STC cycle without CH , the introduction of methane yields a much higher hydrogen production, especially at the lower temperature range and atmospheric pressure. In the oxidation step, a moderately excessive water is beneficial for energy conversion whether in isothermal or non-isothermal operations, especially at H O: Mo= 4. In the whole STC cycle, the maximum non-isothermal and isothermal efficiency can reach 0.417 and 0.391 respectively. In addition, the predicted efficiency of the second cycle is also as high as 0.454 at = 1200 K and = 400 K, indicating that MoO could be a new and potential candidate for obtaining solar fuel by methane reduction.

关键词： MoO2/Mo based on solar thermochemical cycle     methanothermal reduction     isothermal and non-isothermal operation     syngas and hydrogen production     thermodynamic analysis    

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Hydrogen production from water splitting on CdS-based photocatalysts using solar light

Xiaoping CHEN, Wenfeng SHANGGUAN

《能源前沿（英文）》 2013年 第7卷 第1期   页码 111-118 doi: 10.1007/s11708-012-0228-4

摘要： Hydrogen energy has been regarded as the most promising energy resource in the near future due to that it is a clean and sustainable energy. And the heterogeneous photocatalytic hydrogen production is increasingly becoming a research hotspot around the world today. As visible light response photocatalysts for hydrogen production, cadmium sulfide (CdS) is the most representative material, the research of which is of continuing popularity. In the past several years, there has been significant progress in water splitting on CdS-based photocatalysts using solar light, especially in the development of co-catalysts. In this paper, recent researches into photocatalytic water splitting on CdS-based photocatalysts are reviewed, including controllable synthesis of CdS, modifications with different kinds of cocatalysts, solid solution, intercalated with layered nanocomposites and metal oxides, and hybrids with graphenes etc. Finally, the problems and future challenges in photocatalytic water splitting on CdS-based photocatalysts are described.

关键词： hydrogen     photocatalysis     solar conversion     cadmium sulfide (CdS) complex    

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Energy supply for water electrolysis systems using wind and solar energy to produce hydrogen: a case

Mostafa REZAEI, Ali MOSTAFAEIPOUR, Mojtaba QOLIPOUR, Mozhgan MOMENI

《能源前沿（英文）》 2019年 第13卷 第3期   页码 539-550 doi: 10.1007/s11708-019-0635-x

摘要： Due to acute problems caused by fossil fuels that threaten the environment, conducting research on other types of energy carriers that are clean and renewable is of great importance. Since in the past few years hydrogen has been introduced as the future fuel, the aim of this study is to evaluate wind and solar energy potentials in prone areas of Iran by the Weibull distribution function (WDF) and the Angstrom-Prescott (AP) equation for hydrogen production. To this end, the meteorological data of solar radiation and wind speed recorded at 10 m height in the time interval of 3 h in a five-year period have been used. The findings indicate that Manjil and Zahedan with yearly wind and solar energy densities of 6004 (kWh/m ) and 2247 (kWh/m ), respectively, have the greatest amount of energy among the other cities. After examining three different types of commercial wind turbines and photovoltaic (PV) systems, it becomes clear that by utilizing one set of Gamesa G47 turbine, 91 kg/d of hydrogen, which provides energy for 91 car/week, can be produced in Manjil and will save about 1347 L of gasoline in the week. Besides, by installing one thousand sets of X21-345 PV systems in Zahedan, 20 kg/d of hydrogen, enough for 20 cars per week, can be generated and 296 L of gasoline can be saved. Finally, the RETScreen software is used to calculate the annual CO emission reduction after replacing gasoline with the produced hydrogen.

关键词： wind energy     solar energy     water electrolysis     hydrogen production     Weibull distribution function (WDF)     Angstrom-Prescott (AP) equation    

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Theoretical study on flow and radiation in tubular solar photocatalytic reactor

《能源前沿（英文）》 2021年 第15卷 第3期   页码 687-699 doi: 10.1007/s11708-021-0773-9

摘要： In this paper, based on the mixture flow model, an optimized six-flux model is first established and applied to the tubular solar photocatalytic reactor. Parameters influencing photocatalyst distribution and radiation distribution at the reactor outlet, viz. catalyst concentration and circulation speed, are also analyzed. It is found that, at the outlet of the reactor, the optimized six-flux model has better performances (the energy increase by 1900% and 284%, respectively) with a higher catalyst concentration (triple) and a lower speed (one third).

关键词： photocatalytic hydrogen photoreactor     nume- rical simulation     solar energy     flow model     radiation model    

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Toward better understanding vacuum ultraviolet–iodide induced photolysis via hydrogen peroxide formation

《环境科学与工程前沿（英文）》 2022年 第16卷 第5期 doi: 10.1007/s11783-021-1489-0

摘要：

• UV/VUV/I– induces substantial H2O2 and IO3– formation, but UV/I– does not.

关键词： Vacuum ultraviolet     Hydrogen peroxide     Iodate     Hydroxyl radical     Redox transition    

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Enhanced activity of bimetallic Fe-Cu catalysts supported on ceria toward water gas shift reaction: synergistic

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 1962-1972 doi: 10.1007/s11705-023-2359-z

摘要： Within the “hydrogen chain”, the high-temperature water gas shift reaction represents a key step to improve the H2 yield and adjust the H2/COx ratio to fit the constraints of downstream processes. Despite the commercial application of the high-temperature water gas shift, novel catalysts characterized by higher intrinsic activity (especially at low temperatures), good thermal stability, and no chromium content are needed. In this work, we propose bimetallic iron-copper catalysts supported on ceria, characterized by low active phase content (iron oxide + copper oxide < 5 wt %). Fresh and used samples were characterized by inductively coupled plasma mass spectrometry, X-ray diffraction, nitrogen physisorption, scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy, and temperature programmed reduction in hydrogen to relate physicochemical features and catalytic activity. The sample with iron/copper ≈ 1 and 4 wt % active phase content showed the best catalytic properties in terms of turnover frequency, no methane formation, and stability. Its unique properties were due to both strong iron-copper interaction and strong metal-support interaction, leading to outstanding redox behavior.

关键词： water gas shift     iron     copper     bimetallic catalysts     ceria     hydrogen    

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Rational design on photoelectrodes and devices to boost photoelectrochemical performance of solar-driven

《化学科学与工程前沿（英文）》 2022年 第16卷 第6期   页码 777-798 doi: 10.1007/s11705-022-2148-0

摘要： As an eco-friendly, efficient, and low-cost technique, photoelectrochemical water splitting has attracted growing interest in the production of clean and sustainable hydrogen by the conversion of abundant solar energy. In the photoelectrochemical system, the photoelectrode plays a vital role in absorbing the energy of sunlight to trigger the water splitting process and the overall efficiency depends largely on the integration and design of photoelectrochemical devices. In recent years, the optimization of photoelectrodes and photoelectrochemical devices to achieve highly efficient hydrogen production has been extensively investigated. In this paper, a concise review of recent advances in the modification of nanostructured photoelectrodes and the design of photoelectrochemical devices is presented. Meanwhile, the general principles of structural and morphological factors in altering the photoelectrochemical performance of photoelectrodes are discussed. Furthermore, the performance indicators and first principles to describe the behaviors of charge carriers are analyzed, which will be of profound guiding significance to increasing the overall efficiency of the photoelectrochemical water splitting system. Finally, current challenges and prospects for an in-depth understanding of reaction mechanisms using advanced characterization technologies and potential strategies for developing novel photoelectrodes and advanced photoelectrochemical water splitting devices are demonstrated.

关键词： photoelectrochemical water splitting     photoelectrodes     hydrogen production     charge separation     catalytic mechanism    

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钽基氮氧化物——窄带隙光催化剂用于太阳能制氢 Review

肖慕, 王松灿, Thaweesak Supphasin, 罗彬, 王连洲

《工程（英文）》 2017年 第3卷 第3期   页码 365-378 doi: 10.1016/J.ENG.2017.03.019

摘要：

光催化分解水可以将太阳能直接转化为氢能，是一种有效利用太阳能的途径。开发用于太阳能制氢的高效且稳定的光催化剂是光催化研究领域的重要目标之一。钽基氮氧化物具有窄的带隙宽度，并且光生电子和空穴的势能足够用来分解水，因此该类光催化剂最有可能实现太阳能制氢。到目前为止，全世界的研究小组对钽基氮氧化物光催化剂进行了系统而深入的研究，取得了大量的成果。然而，钽基氮氧化物的太阳能制氢效率还远远低于理论值。如何更好地设计这些材料进而提高其太阳能制氢效率这一命题是十分重要和有意义的。本文总结了钽基氮氧化物用于光催化制氢的研究和发展过程，着重分析了用于提高光催化分解水效率的各种方法。最后，探讨了窄带隙钽基氮氧化物光催化分解水研究领域的未来发展趋势。

关键词： 钽基光催化剂     窄带隙     分解水     氢    

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Impact of thermal processes on multi-crystalline silicon

Moonyong KIM,Phillip HAMER,Hongzhao LI,David PAYNE,Stuart WENHAM,Malcolm ABBOTT,Brett HALLAM

《能源前沿（英文）》 2017年 第11卷 第1期   页码 32-41 doi: 10.1007/s11708-016-0427-5

摘要： Fabrication of modern multi-crystalline silicon solar cells involves multiple processes that are thermally intensive. These include emitter diffusion, thermal oxidation and firing of the metal contacts. This paper illustrates the variation and potential effects upon recombination in the wafers due to these thermal processes. The use of light emitter diffusions more compatible with selective emitter designs had a more detrimental effect on the bulk lifetime of the silicon than that of heavier diffusions compatible with a homogenous emitter design and screen-printed contacts. This was primarily due to a reduced effectiveness of gettering for the light emitter. This reduction in lifetime could be mitigated through the use of a dedicated gettering process applied before emitter diffusion. Thermal oxidations could greatly improve surface passivation in the intra-grain regions, with the higher temperatures yielding the highest quality surface passivation. However, the higher temperatures also led to an increase in bulk recombination either due to a reduced effectiveness of gettering, or due to the presence of a thicker oxide layer, which may interrupt hydrogen passivation. The effects of fast firing were separated into thermal effects and hydrogenation effects. While hydrogen can passivate defects hence improving the performance, thermal effects during fast firing can dissolve precipitating impurities such as iron or de-getter impurities hence lower the performance, leading to a poisoning of the intra-grain regions.

关键词： gettering     grain boundaries     hydrogen     impurities     oxidation     passivation     solar cell    

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Defect passivation on cast-mono crystalline screen-printed cells

Alison WENHAM,Lihui SONG,Malcolm ABBOTT,Iskra ZAFIROVSKA,Sisi WANG,Brett HALLAM,Catherine CHAN,Allen BARNETT,Stuart WENHAM

《能源前沿（英文）》 2017年 第11卷 第1期   页码 60-66 doi: 10.1007/s11708-016-0443-5

摘要： Cast-mono crystalline silicon wafers contain crystallographic defects, which can severely impact the electrical performance of solar cells. This paper demonstrates that applying hydrogenation processes at moderate temperatures to finished screen print cells can passivate dislocation clusters within the cast-mono crystalline silicon wafers far better than the hydrogenation received during standard commercial firing conditions. Efficiency enhancements of up to 2% absolute are demonstrated on wafers with high dislocation densities. The impact of illumination to manipulate the charge state of hydrogen during annealing is investigated and found to not be significant on the wafers used in this study. This finding is contrary to a previous study on similar wafers that concluded increased H or H from laser illumination was responsible for the further passivation of positively charged dangling bonds within the dislocation clusters.

关键词： silicon solar cell     dislocation     cast-mono     laser     hydrogen passivation    

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标题 作者 时间 类型 操作

Approaching the commercial threshold of solar water splitting toward hydrogen by III-nitrides nanowires

期刊论文

Ga(X)N/Si nanoarchitecture: An emerging semiconductor platform for sunlight-powered water splitting towardhydrogen

期刊论文

Photocatalysis: from solar light to hydrogen energy

期刊论文

Unravelling the bottleneck of phosphonic acid anchoring groups aiming toward enhancing the stabilityand efficiency of mesoscopic solar cells

期刊论文

Revisiting solar hydrogen production through photovoltaic-electrocatalytic and photoelectrochemical water

期刊论文

Thermodynamic assessment of hydrogen production via solar thermochemical cycle based on MoO

Jiahui JIN, Lei WANG, Mingkai FU, Xin LI, Yuanwei LU

期刊论文

Hydrogen production from water splitting on CdS-based photocatalysts using solar light

Xiaoping CHEN, Wenfeng SHANGGUAN

期刊论文

Energy supply for water electrolysis systems using wind and solar energy to produce hydrogen: a case

Mostafa REZAEI, Ali MOSTAFAEIPOUR, Mojtaba QOLIPOUR, Mozhgan MOMENI

期刊论文

Theoretical study on flow and radiation in tubular solar photocatalytic reactor

期刊论文

Toward better understanding vacuum ultraviolet–iodide induced photolysis via hydrogen peroxide formation

期刊论文

Enhanced activity of bimetallic Fe-Cu catalysts supported on ceria toward water gas shift reaction: synergistic

期刊论文

Rational design on photoelectrodes and devices to boost photoelectrochemical performance of solar-driven

期刊论文

钽基氮氧化物——窄带隙光催化剂用于太阳能制氢

肖慕, 王松灿, Thaweesak Supphasin, 罗彬, 王连洲

期刊论文

Impact of thermal processes on multi-crystalline silicon

Moonyong KIM,Phillip HAMER,Hongzhao LI,David PAYNE,Stuart WENHAM,Malcolm ABBOTT,Brett HALLAM

期刊论文

Defect passivation on cast-mono crystalline screen-printed cells

Alison WENHAM,Lihui SONG,Malcolm ABBOTT,Iskra ZAFIROVSKA,Sisi WANG,Brett HALLAM,Catherine CHAN,Allen BARNETT,Stuart WENHAM

期刊论文